YEAST
Belgian yeast is very distinctive, unlike the two other major components of beer which are fairly standard but applied in unusual ways. Trappist ale yeasts create what could be considered a very high level of esters, iso-amyl acetate (associated with the taste and aroma of bananas) in particular. The same could be said of many Specials who's flavor profiles mimic that of a Tripel. Lactic acid production is another very unusual aspect of Belgian yeast activity. The resulting sourness can be found in a wide range of brews. Lambics, some Brown ales, some Red ales, and some Specials can be examples of this.
If I was only allowed to offer one "tip" to somebody wanting to improve there Belgian-style home brewing it would be pitch more yeast. Now-a-days I won't brew a Trippel if I can pitch a quart slurry. This does not mean a quart of fliud with yeast on the bottom, it means a quart bottle with an inch of fluid on the top and the rest is yeast. You can get this by harvesting the sludge at the bottom of a carboy following the primary fermentation. Beleive me, the difference between this approach and the infinitesimal amount in a gold pouch is enormous.
One more thing, if you are finding a normally high ester beer - like a Trippel - is coming out solventy the answer may be areation. Brewers Resource sells an inexpensive device that is specifically designed to areate wort before or after pitching. There are few things for $30 you can buy that will improve your beer more.
The tremendous diversity of Belgian yeast can best be summed up by the list of different strains available to the home brewer. These can generally be purchased at you brew supply store except for Brewtec and Williams. You must contact Brewers Resource and Williams Brewing respectively.